Conformationally Locked Tolans, β‑Sheet Structures, and Photophysical Properties
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https://figshare.com/articles/dataset/Conformationally_Locked_Tolans_Sheet_Structures_and_Photophysical_Properties/2097820
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资源简介:
Conformationally
locked tetrasubstituted tolans were synthesized
by introducing a tether on the tolan. To demonstrate the utilities
of these motifs, a β-hairpin structure (15) was
synthesized, and its additional stabilizing effects were evaluated.
Moreover, the photophysical properties of cyclic tolans and their
β-sheet structure were investigated. The fluorescence quantum
yield of cyclic tolan 12 is >1000 times stronger than
its congener 1 in CH3CN.
创建时间:
2016-02-12



