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Emissive Metallomesogens Based on 2-Phenylpyridine Complexes of Iridium(III)

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https://figshare.com/articles/dataset/Emissive_Metallomesogens_Based_on_2_Phenylpyridine_Complexes_of_Iridium_III_/2664523
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Preparation of IrIII complexes using anisotropic 2,5-di(4-alkoxyphenyl)pyridine ligands leads to emissive, liquid-crystalline complexes containing bound Cl and dimethyl sulfoxide. Using analogous poly(alkoxy) ligands allows the preparation of bis(2-phenylpyridine)iridium(III) acac complexes, which are also mesomorphic. The observation of liquid crystallinity in octahedral complexes of this type is without precedent.
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2016-02-23
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