Alkylation of Rhodium Porphyrins Using Ammonium and Quinolinium Salts
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https://figshare.com/articles/dataset/Alkylation_of_Rhodium_Porphyrins_Using_Ammonium_and_Quinolinium_Salts/2270557
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资源简介：
Alkylation of rhodium(III) porphyrins [RhIII(por)]
was achieved under relatively mild conditions in up to 98% yields,
where readily available ammonium and quinolinium salts were utilized
as the alkylating agents. This transformation tolerates air and water,
thus serving as a convenient method to prepare a variety of alkyl-
and benzyl-RhIII(por) complexes. Preliminary mechanistic
studies support an SN2-like reaction pathway involving
a RhI(por) anion intermediate.
创建时间：
2014-07-28
