Sequence and Regularity Controlled Coordination Copolymerization of Butadiene and Styrene: Strategy and Mechanism
收藏NIAID Data Ecosystem2026-03-10 收录
下载链接：
https://figshare.com/articles/dataset/Sequence_and_Regularity_Controlled_Coordination_Copolymerization_of_Butadiene_and_Styrene_Strategy_and_Mechanism/4561057
下载链接
链接失效反馈官方服务：
资源简介：
The
stereoselective and sequence controlled coordination copolymerizations
of butadiene (BD) and styrene (St) with diblock, tapered, gradient,
and random sequence distributions were achieved for the first time
through varying the central metals of the rare-earth metal bis(alkyl)
catalyst precursors (Flu-CH2-Py)Ln(CH2SiMe3)2(THF)x (Flu = fluorenyl, Py = pyridyl, x = 1: Ln = Nd(1), Y(2), Tm(3); x = 0, Ln = Sc(4)). The thermal behavior, morphology,
and the mechanical property of these copolymers were analyzed, and
their relationships were established for the first time. The mechanism
of central metal size tuning the sequence distribution was discussed
based on DFT calculations.
创建时间：
2017-01-18
