Structure and Properties of New Mixed-Valent [MnIII2MnIV3LnIII5O5] Complexes (LnIII = TmIII, LuIII, and YbIII)
收藏Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Structure_and_Properties_of_New_Mixed_Valent_Mn_sup_III_sup_sub_2_sub_Mn_sup_IV_sup_sub_3_sub_Ln_sup_III_sup_sub_5_sub_O_sub_5_sub_Complexes_Ln_sup_III_sup_Tm_sup_III_sup_Lu_sup_III_sup_and_Yb_sup_III_sup_/2535877
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资源简介：
By using 2′-hydroxyacetophenoxime, a new family of complexes with an [MnIII2MnIV3Ln5O5] core was obtained with Ln = Tm (1), Lu (2), and Yb (3). Heterometallic Mn/Tm and Mn/Lu combinations have had no precedence so far. Studies of the magnetic properties indicate the presence of intracomplex antiferromagnetic interactions in 1 and 3, as well as a dominating ferromagnetic interaction between MnIII and MnIV spins in 2, leading to an ST = 5/2 ground state.
创建时间：
2016-02-21
