Locked Planarity: A Strategy for Tailoring Ladder-Type π‑Conjugated Anilido–Pyridine Boron Difluorides
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https://figshare.com/articles/dataset/Locked_Planarity_A_Strategy_for_Tailoring_Ladder_Type_Conjugated_Anilido_Pyridine_Boron_Difluorides/2336311
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资源简介：
A novel series of syn- and anti-ladder-type anilido–pyridine
boron difluorides (APBDs) were
synthesized by stepwise incorporation of boron into laddered ligands.
The boron coordination-locked strategy endows the ladder-type APBDs
with a stiff conformation, which results in a substantial bathochromic
shift of their absorption spectra and a narrowed HOMO–LUMO
energy gap, reinforcing the compounds for potential applications in
organic electronics.
创建时间：
2016-02-18
