Synthesis, Characterization, and Catalytic Activity of Alcohol-Functionalized NHC Gold(I/III) Complexes
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https://figshare.com/articles/dataset/Synthesis_Characterization_and_Catalytic_Activity_of_Alcohol_Functionalized_NHC_Gold_I_III_Complexes/2298541
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资源简介：
A series of alcohol-functionalized
NHC gold(I/III) complexes of the types [(L)Au(Cl or NTf2)] and [(L)AuCl3] (L = IPrEtOH, (1, 4, 5), IMesEtOH (2, 6), IMeEtOH (3, 7)) was readily synthesized
and characterized by NMR spectroscopy and single-crystal X-ray diffraction.
The catalytic activity of the new complexes was assessed and compared
with that of other gold catalysts, in the tandem 3,3-rearrangement–Nazarov
reactions of enynyl acetate and the rearrangement reaction of alkynyloxirane.
The new complexes appeared to be dual-site catalysts in both transformations, thanks to the presence of the primary alcohol function
tethered to the NHC ligands.
创建时间：
2016-02-17
