Mild and Chemoselective Synthesis of Lactones from Diols Using a Novel Metal−Ligand Bifunctional Catalyst
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下载链接：
https://figshare.com/articles/dataset/Mild_and_Chemoselective_Synthesis_of_Lactones_from_Diols_Using_a_Novel_Metal_Ligand_Bifunctional_Catalyst/3743037
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资源简介：
A novel amino alcohol-based Ir bifunctional complex acts as an efficient catalyst for oxidative lactonization of 1,4- or 1,5-diols with a substrate-to-catalyst molar ratio of 200−1000 in acetone or butanone. The reaction proceeds with broad functional group tolerance to give lactone in
high yield at room temperature. The catalyst precursor Cp*IrCl[OCH2C(C6H5)2NH2] is isolated and characterized by a single-crystal X-ray analysis.
创建时间：
2016-08-20
