Sn-Free Ni-Catalyzed Reductive Coupling of Glycosyl Bromides with Activated Alkenes
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https://figshare.com/articles/dataset/Sn_Free_Ni_Catalyzed_Reductive_Coupling_of_Glycosyl_Bromides_with_Activated_Alkenes/2877376
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资源简介：
A mild, stereoselective method for the Ni-catalyzed synthesis of α-C-alkylglycosides is reported. This approach entails the reductive coupling of glycosyl bromides with activated alkenes at room temperature, with low alkene loading as an important feature. Diastereoselective coupling with 2-substituted acrylate derivatives was made possible through the use of 2,4-dimethyl-3-pentanol as a proton source.
创建时间：
2009-02-19
