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Formation and Structure of <i>fac</i>-[Mo(CO)<sub>3</sub>(C<sub>2</sub>H<sub>2</sub>[N(CH<sub>2</sub>Bu<sup>t</sup>)]<sub>2</sub>Ge)<sub>3</sub>]: The First Structurally Characterized Group 6 Transition Metal Complex of an Unsaturated Diaminogermylene

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The title compound was obtained from the cyclic diaminogermylene C2H2[N(CH2But)]2Ge and cis-[Mo(CO)4(NCEt)2] and its crystal structure determined revealing structural changes in the coordinated ligand indicative of strong π-acceptor properties.

创建时间:
2016-08-17
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