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Polyethylated Triptycene Derivatives

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Polyethylated_Triptycene_Derivatives/3696054
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The octaethyl triptycenes 7 and 8 were synthesized by Diels−Alder reaction of the octaethylanthracene 4 with the corresponding benzynes. Low-temperature NMR spectra of 7 and 8 are consistent with the presence of the fully alternated conformation “a” of C2 symmetry. However, in the determined crystal structures, the compounds adopt a higher energy conformation with a pair of vicinal ethyls oriented in the same direction.
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2016-08-19
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