Silver-Catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides with β-Boryl Acrylates
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https://figshare.com/articles/dataset/Silver_Catalyzed_1_3_Dipolar_Cycloaddition_of_Azomethine_Ylides_with_Boryl_Acrylates/2681620
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资源简介:
The Ag-catalyzed 1,3-dipolar cycloaddition of (Ε)-β-borylacrylates with azomethine ylides is described. The resulting 3-borylpyrrolidine derivatives were obtained in high yields and complete endo selectivities using AgOAc/dppe as catalyst system and B(dam) as boryl group. Transformation of the B(dam) group into pinacol borane and oxidation afforded 3-hydroxyproline derivatives in high yields.
创建时间:
2016-02-23



