Dramatically Enhanced Carbon Acidity of the Nitrobenzyl Fragment in a Nickel(II) Scorpionate Complex
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https://figshare.com/articles/dataset/Dramatically_Enhanced_Carbon_Acidity_of_the_Nitrobenzyl_Fragment_in_a_Nickel_II_Scorpionate_Complex/3274495
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资源简介：
The −CH2− group of the 2-nitrobenzyl pendant arm of the scorpionate complex I deprotonates in basic aqueous solution (pKa = 10.6), due to
the coordination of the nitronate group to the nickel(II) center. Metal coordination enhances 2-nitrobenzene acidity by 10 orders of magnitude.
创建时间：
2016-05-05
