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Synthesis of 1,1,3-Polyfunctionalized Cyclobutane Derivatives from the Reaction of Sulfur Ylides with Bicyclo[1.1.0]butanes

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NIAID Data Ecosystem2026-05-02 收录
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https://figshare.com/articles/dataset/Synthesis_of_1_1_3-Polyfunctionalized_Cyclobutane_Derivatives_from_the_Reaction_of_Sulfur_Ylides_with_Bicyclo_1_1_0_butanes/26870310
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资源简介:
1,1,3-Polyfunctionalized cyclobutane derivatives have been synthesized from sulfur ylides and bicyclo[1.1.0]butanes (BCBs). This protocol operates under mild reaction conditions without the need for catalysts, generally producing moderate to good yields of syn-addition derivatives with structural diversity. An unexpected intramolecular rearrangement mechanism has also been proposed.
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2024-08-29
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