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Chiral Gold Complex-Catalyzed Hetero-Diels–Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Chiral_Gold_Complex_Catalyzed_Hetero_Diels_Alder_Reaction_of_Diazenes_Highly_Enantioselective_and_General_for_Dienes/2437054
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资源简介:
A chiral gold­(I) complex-catalyzed highly regio- and enantioselective azo hetero-Diels–Alder reaction has been developed. The chiral gold­(I) complex acting as a Lewis acid exhibits high efficiency in the activation of urea-based diazene dienophiles. Moreover, this chiral gold catalyst also rendered a cascade intramolecular enyne cycloisomerization/asymmetric azo-HDA reaction.
创建时间:
2016-02-19
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