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Silver(I)–Ferrophox Catalyzed Enantioselective Desymmetrization of Cyclopentenedione: Synthesis of Highly Substituted Bicyclic Pyrrolidines

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Silver_I_Ferrophox_Catalyzed_Enantioselective_Desymmetrization_of_Cyclopentenedione_Synthesis_of_Highly_Substituted_Bicyclic_Pyrrolidines/2121139
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资源简介:
A highly enantioselective desymmetrization of prochiral cyclopentene-1,3-dione via [3 + 2] cycloaddition of azomethine ylide using a silver­(I)–ferrophox complex has been demonstrated. The method has been utilized in the synthesis of highly functionalized enantioenriched 5,5-fused bicyclic pyrrolidine derivatives under mild reaction conditions.
创建时间:
2016-02-12
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