Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties
收藏Figshare2016-02-23 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Li_sub_4_sub_Cs_sub_3_sub_B_sub_7_sub_O_sub_14_sub_Synthesis_Crystal_Structure_and_Optical_Properties/2680783
下载链接
链接失效反馈官方服务：
资源简介：
A new noncentrosymmetric polyborate, Li4Cs3B7-O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3121 (No. 152) with unit cell parameters of a = 6.9313(6) Å, c = 26.799(3) Å, and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.
创建时间：
2016-02-23
