Total Synthesis of (−)-Chromodorolide B
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https://figshare.com/articles/dataset/Total_Synthesis_of_Chromodorolide_B/2220514
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The first total synthesis of a chromodorolide diterpenoid is described. The synthesis features a bimolecular radical addition/cyclization/fragmentation cascade that unites butenolide and trans-hydrindane fragments while fashioning two C–C bonds and stereoselectively forming three of the ten contiguous stereocenters of chromodorolide B.
创建时间:
2016-02-22



