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A Au(I)-Precatalyst with a Cyclopropenium Counterion: An Unusual Ion Pair

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NIAID Data Ecosystem2026-03-09 收录
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The synthesis and X-ray crystal structure of a novel Au­(I)-precatalyst applied to intermolecular alkyne hydroamination is reported. Density functional theory (DFT) calculations revealed the cyclopropenium counterion of this Au­(I)-precatalyst imparts stability through H-bonding and other noncovalent interactions.

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2016-03-14
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