Phospha-Scorpionate Complexes by Click Chemistry using Phenyl Azide and Ethynylphosphine Oxides
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https://figshare.com/articles/dataset/Phospha_Scorpionate_Complexes_by_Click_Chemistry_using_Phenyl_Azide_and_Ethynylphosphine_Oxides/2928115
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资源简介：
The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.
创建时间：
2016-02-27
