Synthesis, Reactivity, and Catalytic Application of a Nickel Pincer Hydride Complex
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https://figshare.com/articles/dataset/Synthesis_Reactivity_and_Catalytic_Application_of_a_Nickel_Pincer_Hydride_Complex/2537437
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资源简介：
The nickel(II) hydride complex [(MeN2N)Ni-H]
(2) was synthesized by the reaction of [(MeN2N)Ni-OMe] (6) with Ph2SiH2 and was characterized by NMR and IR spectroscopy as well
as X-ray crystallography. 2 was unstable in solution,
and it decomposed via two reaction pathways. The first pathway was
intramolecular N–H reductive elimination to give MeN2NH and nickel particles. The second pathway was intermolecular,
with H2, nickel particles, and a five-coordinate Ni(II)
complex [(MeN2N)2Ni] (8) as the products. 2 reacted with acetone and ethylene,
forming [(MeN2N)Ni-OiPr] (9) and [(MeN2N)Ni-Et] (10), respectively. 2 also reacted with alkyl
halides, yielding nickel halide complexes and alkanes. The reduction
of alkyl halides was rendered catalytically, using [(MeN2N)Ni-Cl] (1) as catalyst, NaOiPr or NaOMe as base, and Ph2SiH2 or Me(EtO)2SiH as the hydride source. The catalysis appears
to operate via a radical mechanism.
创建时间：
2016-02-21
