Iridium-Catalyzed Borylation of Pyrene: Irreversibility and the Influence of Ligand on Selectivity
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The iridium-catalyzed borylation of pyrene, using 4,4′-dimethyl-2,2′-bipyridine as the ligand, in the presence of t-BuOK, gave a mixture of 2,4,7,9-tetrakis(Bpin)pyrene (c4) and its 2,4,7,10-isomer (m4) in a 2.2:1 ratio, and the selectivity of the Ir-catalyzed borylation of pyrene is kinetically determined and can be influenced to some extent by the nature of the ligand.
创建时间：
2016-02-16
