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Grid Expansion: a Rhombiclike [L4Fe2(Ag2)2] Complex Containing Ag2 Dumbbells at Two Vertices

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Grid_Expansion_a_Rhombiclike_L_sub_4_sub_Fe_sub_2_sub_Ag_sub_2_sub_sub_2_sub_Complex_Containing_Ag_sub_2_sub_Dumbbells_at_Two_Vertices/2543167
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The pyrazolate-based ditopic ligand HL forms a strongly hydrogen-bonded corner complex dimer [FeII(HL)2]2(BF4)4 (1) with a [2 × 2] gridlike arrangement of four ligand strands. The two empty vertices can then be filled with {Ag2}2+ dumbbells, yielding the unprecedented diferric complex [L4FeIII2(AgI2)2]­(BF4)6 (2) that features a rhombiclike structure with an almost planar hexagon of metal ions.
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2016-02-22
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