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Catalytic Annulation of Diethyl Methylenecyclopropane-1,1-dicarboxylate with 1,1-Dicyanoalkenes

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Figshare2017-05-01 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Annulation_of_Diethyl_Methylenecyclopropane-1_1-dicarboxylate_with_1_1-Dicyanoalkenes/4956527
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The catalytic annulation of methylenecyclopropane 1 with 1,1-dicyanoalkenes 2 using a Mg–Sn catalytic system was developed. Selective formation of cyclopentylidenemalonates 3 and spiro­[2,3]­hexane-1,1-dicarboxylates 4 was accomplished via the choice of a proper solvent and an effective catalytic system.
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2017-05-01
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