Potassium Iodide-Promoted One-Pot Synthesis of Fluoroalkylated Quinoxalines via a Tandem Michael Addition/Azidation/Cycloamination Approach
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https://figshare.com/articles/dataset/Potassium_Iodide-Promoted_One-Pot_Synthesis_of_Fluoroalkylated_Quinoxalines_via_a_Tandem_Michael_Addition_Azidation_Cycloamination_Approach/6890651
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Fluoroalkylated quinoxlines with various groups were efficiently synthesized via a one-pot tandem Michael addition/azidation/cycloamination process. Under the mild and metal-free conditions, a bis-imine intermediate (4a) was detected and isolated for the first time. KI played a crucial role in this reaction. The mechanism was described.
创建时间：
2018-08-01
