A Stable Coordination Complex of Rh(IV) in an N,O-Donor Environment
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https://figshare.com/articles/dataset/A_Stable_Coordination_Complex_of_Rh_IV_in_an_N_O_Donor_Environment/2095597
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资源简介：
We
describe facial and meridional isomers of [RhIII(pyalk)3], as well as meridional [RhIV(pyalk)3]+ {pyalk =2-(2-pyridyl)-2-propanoate}, the first coordination
complex in an N,O-donor environment to show a clean, reversible RhIII/IV redox couple and to have a stable Rh(IV) form, which
we characterize by EPR and UV–visible spectroscopy as well
as X-ray crystallography. The unprecedented stability of the Rh(IV)
species is ascribed to the exceptional donor strength of the ligands,
their oxidation resistance, and the meridional coordination geometry.
创建时间：
2016-02-12
