Chiral Holmium Complex-Catalyzed Diels–Alder Reaction of Silyloxyvinylindoles: Stereoselective Synthesis of Hydrocarbazoles
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https://figshare.com/articles/dataset/Chiral_Holmium_Complex_Catalyzed_Diels_Alder_Reaction_of_Silyloxyvinylindoles_Stereoselective_Synthesis_of_Hydrocarbazoles/2365363
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资源简介：
The catalytic and asymmetric cycloaddition between 3-[1-(silyloxy)vinyl]indoles and electron-deficient olefins gave substituted hydrocarbazoles in up to 99% yield and 94% ee. This reaction was catalyzed by a novel chiral holmium(III) complex. Alkylation of the cycloadduct gave a tricyclic compound with four continuous chiral centers, one of which was a quaternary carbon.
创建时间：
2016-02-18
