Stable Cationic Dimethyl(hydrido)platinum(IV) Complex
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https://figshare.com/articles/dataset/Stable_Cationic_Dimethyl_hydrido_platinum_IV_Complex/3784677
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资源简介：
The complex [PtMe2(9N3)], 1, 9N3 = 1,4,7-triazacyclononane, undergoes protonation by
triflic acid and, reversibly, even by methanol to form the cationic complex [PtHMe2(9N3)]+,
2, which is thermally stable up to 190 °C in the solid state as the triflate salt. Oxidation of
1 or 2 by H2O2 or by H2O/O2 gives the hydroxy complex [Pt(OH)Me2(9N3)]+, which can be
reversibly protonated to the aqua complex [Pt(OH2)Me2(9N3)]2+.
创建时间：
2016-08-27
