[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4‑4-Et)5, nacnac = HC[C(Me)N-(C6H3)‑2,6‑iPr2]2)
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https://figshare.com/articles/dataset/_Cp_sup_Ar_sup_Ni_Ga_nacnac_An_Open_Shell_Nickel_I_Complex_Supported_by_a_Gallium_I_Carbenoid_Cp_sup_Ar_sup_C_sub_5_sub_C_sub_6_sub_H_sub_4_sub_4_Et_sub_5_sub_nacnac_HC_C_Me_N_C_sub_6_sub_H_sub_3_sub_2_6_i_i_i_Pr_sub_2_sub_sub_2_sub_/3085567
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The 17 valence electron (VE) open-shell nickel gallanediyl complex [CpArNi{Ga(nacnac)}] (3, Ar = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N(C6H3-2,6-iPr2)]2), having an unsupported Ni–Ga bond, was synthesized from [CpArNi(μ-Br)]2 (1) by reducing the adduct [CpArNi(μ-Br){Ga(nacnac)}] (2) or, alternatively, trapping the “CpArNiI” synthon with Ga(nacnac); spectroscopic and DFT studies showed that the single unpaired electron in 3 resides mainly at the Ni center.
创建时间：
2016-03-15
