Mononuclear and Mixed-Metal Dimethyltin Pacman Complexes of a Schiff-Base Pyrrole Macrocycle
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https://figshare.com/articles/dataset/Mononuclear_and_Mixed_Metal_Dimethyltin_Pacman_Complexes_of_a_Schiff_Base_Pyrrole_Macrocycle/2790391
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资源简介：
The synthesis of the dialkyltin complex [SnMe2(H2L)] of an octadentate Schiff-base pyrrole macrocycle is described in which the gross Pacman geometry enforces structural discrimination between the two methyl groups. The presence of the metal-free compartment engenders the formation of mixed-metal Sn−Fe and Sn−Zn complexes in which the macrocyclic cleft has distorted considerably upon the introduction of the transition metal cation.
创建时间：
2016-02-25
