Mononuclear and Mixed-Metal Dimethyltin Pacman Complexes of a Schiff-Base Pyrrole Macrocycle
收藏NIAID Data Ecosystem2026-03-06 收录
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The synthesis of the dialkyltin complex [SnMe2(H2L)] of an octadentate Schiff-base pyrrole macrocycle is described in which the gross Pacman geometry enforces structural discrimination between the two methyl groups. The presence of the metal-free compartment engenders the formation of mixed-metal Sn−Fe and Sn−Zn complexes in which the macrocyclic cleft has distorted considerably upon the introduction of the transition metal cation.
创建时间：
2016-02-25
