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Luminescent Triarylboron-Functionalized Zinc Carboxylate Metal–Organic Framework

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Luminescent_Triarylboron_Functionalized_Zinc_Carboxylate_Metal_Organic_Framework/2442361
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A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal–organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a ZnIIB-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N2, argon, and CO2.
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2016-02-19
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