Rhodium Complexes Bearing 1,10-Phenanthroline Analogue Bis-NHC Ligands Are Active Catalysts for Transfer Hydrogenation of Ketones
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https://figshare.com/articles/dataset/Rhodium_Complexes_Bearing_1_10_Phenanthroline_Analogue_Bis_NHC_Ligands_Are_Active_Catalysts_for_Transfer_Hydrogenation_of_Ketones/2470369
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资源简介：
Synthesis of a new example of the pyridazine annelated
bis(N-heterocyclic carbene) ligand 3b (vegi) bearing
benzyl substituents is reported, as well as the synthesis of its cationic
Rh(cod) complex 5b. The mechanism of formation of the
[Rh(cod)(vegi)]+ complexes was investigated, showing a
stepwise deprotonation of the imidazolium moieties via the mono-carbene
imidazolium Rh(cod)Cl species 4. The [Rh(cod)(vegi)]+ complexes 5a,b show catalytic activity
in the transfer hydrogenation of even sterically hindered ketones.
创建时间：
2016-02-20
