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Anionic Guests in Prismatic Cavities Generated by Enneanuclear Nickel Metallacycles

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Anionic_Guests_in_Prismatic_Cavities_Generated_by_Enneanuclear_Nickel_Metallacycles/2330779
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The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni9} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.
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2016-02-18
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