Synthesis of π-Extended Thiadiazole (Oxides) and Their Electronic Properties
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The syntheses of extended thiadiazole, thiadiazole oxide, and thiadiazole dioxide heterocycles are described. The electron-accepting heterocycles were investigated by X-ray crystallography and optical as well as electrochemical measurements and supported by DFT calculations. The thiadiazole dioxide heterocycles have reduction potentials of −0.7 V vs ferrocene/ferrocenium, suggesting a viable building block for n-type organic materials.
创建时间：
2016-02-24
