Luminescent Coordination Polymers for Highly Sensitive Detection of Nitrobenzene
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Three new luminescent coordination polymers (CPs), [Ag2(bpp)(Hsba)]·H2O (1), [Cd(bpp)(Hsba)·H2O] (2), and [Pb(bpp)3(H2sba)2] (3) (bpp = 1,3-bis(4-pyridyl)propane, H3sba = 2,4-dichloro-5-sulfamoylbenzoic acid), have been designed and synthesized by hydrothermal methods. Compound 1 exhibits left- and right-handed helical chains. Compound 2 shows a 2-fold parallel interpenetration sql net with 44·62 topology. Compound 3 displays a supramolecular wavelike chain. These three title CPs are used as fluorescence sensors for highly selective and sensitive detection of nitrobenzene in a wide linear detection range.
创建时间：
2016-02-13
