Cobalt-Catalyzed Hydrosilylation/Cyclization of 1,6-Enynes
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https://figshare.com/articles/dataset/Cobalt-Catalyzed_Hydrosilylation_Cyclization_of_1_6-Enynes/3833856
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资源简介：
An iminopyridine
cobalt dichloride complex was synthesized and
demonstrated as an effective precatalyst for hydrosilylation/cyclization
of 1,6-enynes with silanes. Various functional groups such as amine,
free aniline, ester, ether, cyano, halide, trifluoromethyl, and heterocycle
were tolerated to afford a variety of silicon-containing compounds.
The reaction could be scaled up to afford products on the gram scale
which could undergo further derivatizations. A primary mechanism was
proposed based on analysis of side products and a deuterated experiment.
创建时间：
2016-10-03
