Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of FeC Covalency in (Me<sub>2</sub>IPr)Fe(NAd)R<sub>2</sub> (R = <sup>neo</sup>Pe, 1‑nor)
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The iron(IV) imide complexes, (Me2IPr)–R2Fe=NAd (R = neoPe (3a), 1-nor (3b)) undergo migratory insertion to iron(II) amides (Me2IPr)RFe{NR(Ad)} (R = neoPe (4a), 1-nor (4b)) without evidence of imidyl or free nitrene character. By increasing the field strength about iron, odd-electron reactivity was circumvented via increased covalency.
创建时间：
2017-08-25
