Studies Toward the Enantiospecific Total Synthesis of Rhodexin A
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https://figshare.com/articles/dataset/Studies_Toward_the_Enantiospecific_Total_Synthesis_of_Rhodexin_A/2391319
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资源简介：
Studies
toward the enantiospecific total synthesis of rhodexin
A via a very hindered inverse electron demand Diels–Alder reaction
are described. The C8-diastereomer of the fully elaborated tetracyclic
core of rhodexin A, 23, was prepared in good yield and
excellent selectivity using as the key step the stepwise Diels–Alder
reaction of the very hindered dienone 3 and the silyl
enol ether 4 catalyzed by the very strong Lewis acid,
dimethylaluminum triflimide.
创建时间：
2016-02-19
