Dialkylaluminum Hydride-Promoted Cyclodimerization of Silylated 1,3-Enynes via Skeletal Rearrangement
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https://figshare.com/articles/dataset/Dialkylaluminum_Hydride_Promoted_Cyclodimerization_of_Silylated_1_3_Enynes_via_Skeletal_Rearrangement/2576152
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资源简介：
The dialkylaluminum hydride-promoted reaction of 1-silylalk-3-en-1-ynes gave symmetrical 1,2,3,5-tetrasubstituted benzenes as single regioisomers. The novel cyclodimerization via skeletal rearrangement can be rationalized by an unprecedented mechanism involving sequential hydroalumination, alkene isomerization, carboalumination, carbon–carbon bond cleavage, and retro-hydroalumination.
创建时间：
2016-02-22
