Probing the Interactions of Transition-Metal Complexes Bound at the Ortho Position of Substituted Biphenyls
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https://figshare.com/articles/dataset/Probing_the_Interactions_of_Transition_Metal_Complexes_Bound_at_the_Ortho_Position_of_Substituted_Biphenyls/3336691
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资源简介：
(4,4‘-dimethylbipyridyl)NiMe2 was found to
react thermally with 2-iodo-2‘,4‘,6‘-trimethylbiphenyl (6)
to produce a C−I insertion that is extremely distorted
from square planarity, with the C−Ni−I plane intersecting the N−Ni−N plane by 33.4°. It was also found that
[(dippe)RhCl]2 reacts with 6 to produce an η3-benzylic
complex by way of a rhodium migration to the methylated ring of the biphenyl unit.
创建时间：
2016-05-07
