Synthesis and Insertion Reactions of the Cyclometalated Palladium−Alkyl Complexes Pd(CH<sub>2</sub>CMe<sub>2</sub>-<i>o</i>-C<sub>6</sub>H<sub>4</sub>)L<sub>2</sub>. Observation of a Pentacoordinated Intermediate in the Insertion of SO<sub>2</sub>
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Palladacycles of the type 2, have been synthesized by treatment of the corresponding chloroalkylcomplexes Pd(CH2CMe2C6H5)ClL2 (L2 = (PMe3)2, 2a, or 1,5-cyclooctadiene (cod), 2b) with suitable bases, or by simple ligand exchange reactions from the cyclooctadiene derivative 2b. The metallacycles 2 react with activated alkynes and with sulfur dioxide, giving rise to different insertion products.
创建时间：
2016-08-17
