Interligand C–C Coupling between α‑Methyl N‑Heterocycles and bipy or phen at Rhenium Tricarbonyl Complexes
收藏数据链接：
官方服务：
资源简介：
Intramolecular C–C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO)3 fragments. The nucleophilic CH2 group generated by the deprotonation attacks the 6 (bipy) or 2 (phen) positions of the diimines, dearomatizing the involved pyridine ring and generating new asymmetric, fac-capping tridentate ligands.
创建时间：
2017-04-03
