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3D GdIII Complex Containing Gd16 Macrocycles Exhibiting Large Magnetocaloric Effect

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/3D_Gd_sup_III_sup_Complex_Containing_Gd_sub_16_sub_Macrocycles_Exhibiting_Large_Magnetocaloric_Effect/2358373
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Hydrothermal synthesis of Gd2O3 and iminodiacetic acid (H2IDA) yields a three-dimensional (3D) complex {[Gd2(IDA)3]·2H2O}n (1) including Gd16 macrocycles. Magnetic investigation indicates the presence of weak antiferromagnetic interaction between GdIII ions and a large magnetocaloric effect with −ΔSmmax = 40.6 J kg–1 K–1.
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2016-02-18
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