3D GdIII Complex Containing Gd16 Macrocycles Exhibiting Large Magnetocaloric Effect
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Hydrothermal synthesis of Gd2O3 and iminodiacetic acid (H2IDA) yields a three-dimensional (3D) complex {[Gd2(IDA)3]·2H2O}n (1) including Gd16 macrocycles. Magnetic investigation indicates the presence of weak antiferromagnetic interaction between GdIII ions and a large magnetocaloric effect with −ΔSmmax = 40.6 J kg–1 K–1.
创建时间：
2016-02-18
