Transition metal-free approach for late-stage benzylic C(sp3)–H etherifications and esterifications

Description of the dataset:

Origin of the data: Experimental spectroscopic measurements
Data Type: experimental measurements, open access supporting information

The data are in CSV, XLSX and FBSW. Supporting information are supplied in PDF format.

Data generated by instruments:  

Varian Cary 5000 UV-Vis-NIR spectrophotometer for UV-Vis measurements,
Varian Cary Eclipse fluorescence spectrophotomer for fluorescence quenching measurements.

Analytical and procedural information: Stern-Volmer fluorescence quenching experiments and UV-Vis measurements.

Definition of variables: Wavelength, Absorbance, Concentration
Units of measurement: nanometers (nm), moles-per-litre (mol/l)

Abbreviations:
File names and data headers use the following abbreviations:

SVQuench refers to Stern-Volmer quenching experiments

MesAcrMe xx refers to data related to the catalyst 9-mesityl-10-methylacridinium. Xx is the amount of catalyst in mol/l (10-4 should be intended as 0.1 mmol/l and so on).

EtAn xx refer to measurements related to 8-ethylanisol. Xx is the amount of quencher in mol/l as above.

BenzAc xx refer to measurements related to benzoic acid. Xx is the amount of quencher in mol/l as above.

Pyrz xx refer to measurements related to pyrazole. Xx is the amount of quencher in mol/l as above.