Structural and Catalytic Performance of a Polyoxometalate-Based Metal−Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block

A polyoxometalate-based lanthanide−organic framework was achieved using the {[Ho4(dpdo)8(H2O)16BW12O40] (H2O)2}7+ nanocage as a secondary building block for the heterogeneous catalysis of phosphodiester cleavage in an aqueous solution.