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[CH<sub>3</sub>NH<sub>2</sub>(CH<sub>2</sub>)<sub>2</sub>NH<sub>2</sub>CH<sub>3</sub>][M<sub>2</sub>(HCOO)<sub>6</sub>] (M = Mn<sup>II</sup> and Co<sup>II</sup>): Weak Ferromagnetic Metal Formate Frameworks of Unique Binodal 6-Connected (4<sup>12</sup>·6<sup>3</sup>)(4<sup>9</sup>·6<sup>6</sup>) Topology, Templated by a Diammonium Cation

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NIAID Data Ecosystem2026-03-06 收录
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Two compounds of [dmenH22+][M2(HCOO)62-] (M = MnII and CoII), synthesized using N,N‘-dimethylethylenediammonium (dmenH22+) as the template, possess anionic metal formate frameworks of a novel binodal 6-connected (412·63)(49·66) topology. They are the first coordination examples of this unique network closely related to niccolite and colquiriite and exhibit 3D long-range antiferromagnetic ordering with small spin canting.

创建时间:
2016-06-03
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