[CH<sub>3</sub>NH<sub>2</sub>(CH<sub>2</sub>)<sub>2</sub>NH<sub>2</sub>CH<sub>3</sub>][M<sub>2</sub>(HCOO)<sub>6</sub>] (M = Mn<sup>II</sup> and Co<sup>II</sup>): Weak Ferromagnetic Metal Formate Frameworks of Unique Binodal 6-Connected (4<sup>12</sup>·6<sup>3</sup>)(4<sup>9</sup>·6<sup>6</sup>) Topology, Templated by a Diammonium Cation
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数据链接:
https://figshare.com/articles/dataset/_CH_sub_3_sub_NH_sub_2_sub_CH_sub_2_sub_sub_2_sub_NH_sub_2_sub_CH_sub_3_sub_M_sub_2_sub_HCOO_sub_6_sub_M_Mn_sup_II_sup_and_Co_sup_II_sup_Weak_Ferromagnetic_Metal_Formate_Frameworks_of_Unique_Binodal_6_Connected_4_sup_12_sup_6_sup_3_sup_4_sup_9_sup_6_sup_6/2980762数据链接链接失效反馈
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资源简介:
Two compounds of [dmenH22+][M2(HCOO)62-] (M = MnII and CoII), synthesized using N,N‘-dimethylethylenediammonium (dmenH22+) as the template, possess anionic metal formate frameworks of a novel binodal 6-connected (412·63)(49·66) topology. They are the first coordination examples of this unique network closely related to niccolite and colquiriite and exhibit 3D long-range antiferromagnetic ordering with small spin canting.
创建时间:
2016-06-03



