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Chemoselective Carbene insertion into the N–H Bond over O–H Bond Using a Well-Defined Single Site (P–P)Cu(I) Catalyst

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NIAID Data Ecosystem2026-03-08 收录
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Phosphine-coordinated air-stable Cu­(I) catalyst (1) has been synthesized and characterized. Catalyst 1 is found to be active toward highly chemoselective carbene insertion into the N–H bond over the O–H bond and also over the formation of olefins when numerous aminophenols were treated with a variety of α-aryl diazoesters under normal experimental conditions.

创建时间:
2016-02-15
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