Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology
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https://figshare.com/articles/dataset/Metal_Organic_Frameworks_Based_on_Trigonal_Prismatic_Building_Blocks_and_the_New_acs_Topology/3288490
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资源简介：
Cationic and mixed-valent forms of Fe3O(CO2)6 trigonal prismatic
clusters have been linked by ditopic links, namely, 1,4-benzenedicarboxylate (1,4-BDC) and 1,3-benzenedicarboxylate (1,3-BDC),
to produce two 3-periodic metal−organic frameworks (MOFs),
[Fe3O(1,4-BDC)3(DMF)3][FeCl4]·(DMF)3 (MOF-235) and Fe3O(1,3-BDC)3(py)3·(py)0.5(H2O)1.5 (MOF-236) (DMF = N,N-dimethylformamide, py = pyridine), respectively. These MOFs exemplify
a new, high-symmetry topology termed acs which we identify here
as the default arrangement for linking trigonal prisms together.
创建时间：
2016-05-06
